alpha-硫丹 基本信息
| 中文名称 | alpha-硫丹 |
|---|---|
| 中文同义词 | A-硫丹;ALPHA-硫丹;alpha-安杀番;苯中Α-硫丹;甲醇中Α-硫丹;ALPHA-硫丹 标准品;内-1,4,5,6,7,7-六氯-5-降冰片烯-2,3-二甲醇环亚硫酸酯;甲苯中Α-硫丹标准品 |
| 英文名称 | Endosulfan I |
| 英文同义词 | 1,4,5,6,7,7-hexachloro-,cyclicsulfite,endo-5-norbornene-3-dimethanol;5-Norbornene-2,3-dimethanol, 1,4,5,6,7,7-hexachloro-, cyclic sulfite, endo-;6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3alpha,5aalpha,6alpha,9alpha,9aalpha)-;6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3alpha,5abeta,6alpha,9alpha,9abeta)-;6,9-methano-2,4,3-benzodioxathiepin,6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-,3-oxide,(3α,5aβ,6α);a-endosulfan-alpha;alpha-Thiodan;endo-1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dimethanol cyclic sulfite |
| CAS号 | 959-98-8 |
| 分子式 | C9H6Cl6O3S |
| 分子量 | 406.93 |
| EINECS号 | 625-034-9 |
| 相关类别 | 分析标准品;有机氯杀虫剂;无机化合物和盐;挥发性有机化合物(VOCs);农残、兽药及化肥类;杀虫剂;Cyclodienes;EA - EO;E-G;Acaricides;Alpha sort;Alphabetic;Analytical Standards;Analytical/Chromatography;2000/60/EC;AcaricidesPesticides;Alpha sort;CyclodienesPesticides&Metabolites;E;EA - EOMethod Specific;E-GAlphabetic;European Community: ISO and DIN;Insecticides;Pesticides;Pesticides&Metabolites;CyclodienesAlphabetic;EA - EOHeterocyclic Building Blocks;S-ContainingMethod Specific;2000/60/ECMore...Close...;Others;Building Blocks;Chemical Synthesis;Chromatography;DIN and DL 152;Environmental Standards;European Community: ISO;Heterocyclic Building Blocks;Metabolites;Method Specific;Pesticides &S-Containing |
| Mol文件 | 959-98-8.mol |
| 结构式 |  |
alpha-硫丹 性质
| 熔点 | 109°C |
|---|---|
| 沸点 | 449.7±45.0 °C(Predicted) |
| 密度 | 1.94 |
| 蒸气压 | 4.58 x 10-5 mmHg at 25 °C (subcooled liquid vapor pressure calculated from GC retention time data,Hinckley et al., 1990) |
| 闪点 | -26 °C |
| 储存条件 | APPROX 4°C |
| 溶解度 | 氯仿：微溶； DMSO：微溶；甲醇：微溶 |
| 水溶解性 | (mg/L): 0.51 at 20 °C (shake flask-GC, Bowman and Sans, 1983) 0.53 at 25 °C (extraction-GLC, Weil et al., 1974) |
| BRN | 2950316 |
| Henry's Law Constant | 0.266 at 5 °C, 0.464 at 15 °C, 0.711 at 20 °C, 0.809 at 25 °C, 1.09 at 35 °C; in 3% NaCl solution:1.07 at 5 °C, 2.08 at 15 °C, 4.71 at 25 °C, 6.71 at 35 °C (gas stripping-GC, Cetin et al., 2006) |
| 暴露限值 | ACGIH TLV: TWA 0.1 mg/m3. |
| 稳定性 | 感光 |
| NIST化学物质信息 | Endosulfan i(959-98-8) |
| EPA化学物质信息 | .alpha.-Endosulfan (959-98-8) |
alpha-硫丹 用途与合成方法
生产方法
可用六氯环戊二烯与丁烯二醇二醋酸酯，经加成、水解及与二氯亚砜反应制得。
安全信息
| 危险品标志 | T,N,Xn,F |
|---|---|
| 危险类别码 | 24/25-36-50/53-25-67-65-62-51/53-48/20-38-11 |
| 安全说明 | 36/37-45-60-61-62-33-29-16-9 |
| 危险品运输编号 | 2761 |
| WGK Germany | 3 |
| RTECS号 | RB9275100 |
| 危险等级 | 6.1(a) |
| 包装类别 | II |
| 毒性 | LC50 (96-hour) for golden orfe 2 mg/L (Hartley and Kidd, 1987), rainbow trout 0.3 mg/L and white sucker 3.0 mg/L (Verschueren, 1983). |
MSDS信息
| 提供商 | 语言 |
|---|---|
endo-1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dimethanol cyclic sulfite | 英文 |
alpha-硫丹 上下游产品信息
上游原料
BETA-硫丹氯化亚砜六氯环戊二烯
